Solvolysis of Phenylacetyl Chlorides in Methanol-Acetonitrile Mixtures 


Vol. 10,  No. 1, pp. 47-50, Jan.  1989


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  Abstract

The methanolysis reactions of phenylacetyl chlorides have been investigated in methanol-acetonitrile mixtures at temperatures ranging - 15.0-0.0℃. Substituent and solvent effects on the rate supported an associative SN2 mechanism for the solvolysis. Activation parameters indicated that the reaction is entropy controlled, while the a/s ratios of the Taft's solvactochromic correlation proved to be remarkably constant with a typical value of 0.50 that is consistent for the reactions proceeding by a typical SN2 path.

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  Cite this article

[IEEE Style]

I. Lee, C. Huh, H. W. Lee, "Solvolysis of Phenylacetyl Chlorides in Methanol-Acetonitrile Mixtures," Bulletin of the Korean Chemical Society, vol. 10, no. 1, pp. 47-50, 1989. DOI: .

[ACM Style]

Ikchoon Lee, Chul Huh, and Hai Whang Lee. 1989. Solvolysis of Phenylacetyl Chlorides in Methanol-Acetonitrile Mixtures. Bulletin of the Korean Chemical Society, 10, 1, (1989), 47-50. DOI: .

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ISSN(Print) 0253-2964
ISSN(Online) 1229-5949