Bistability of CoⅢ(N-N)(3,6-DBSQ)(3,6-DBCat): Subtle Diimine Ligand Effect (N-N=4,7-Dimethyl-1,10-phenanthroline, 5-Chloro-1,10-phenanthroline; DBSQ = Di-tert-butylsemiquinonato; DBCat = Di-tert-butylcatecholato) 


Vol. 15,  No. 8, pp. 641-643, Aug.  1994


PDF
  Abstract

Studies of Co(N-N)(3,6-DBSQ)(3,6-DBCat)(N-N=4,7-dimethyl-1 ,10-phenanthroline, 5-chloro-1,10-phenanthroline; DBSQ=di-tert-butylsemiquinonato; DBCat=di-tert-butylcatecholato) have been carried out on the bistability by intramolecular cobalt-quinone electron transfer in solid state. The title complexes dominantly exist as CdⅢ (N-N)(3,6-DBSQ)(3,6-DBCat) at room temperature and display a significant bistability on temperature variation. Subtle change in optical spectra and magnetic properties is observed when diimine ligands are changed.

  Statistics
Cumulative Counts from November, 2022
Multiple requests among the same browser session are counted as one view. If you mouse over a chart, the values of data points will be shown.


  Cite this article

[IEEE Style]

O. Jung, Y. Lee, Y. Kim, Y. S. Sohn, "Bistability of CoⅢ(N-N)(3,6-DBSQ)(3,6-DBCat): Subtle Diimine Ligand Effect (N-N=4,7-Dimethyl-1,10-phenanthroline, 5-Chloro-1,10-phenanthroline; DBSQ = Di-tert-butylsemiquinonato; DBCat = Di-tert-butylcatecholato)," Bulletin of the Korean Chemical Society, vol. 15, no. 8, pp. 641-643, 1994. DOI: .

[ACM Style]

Ok-Sang Jung, Young-A Lee, Younkyoo Kim, and Youn Soo Sohn. 1994. Bistability of CoⅢ(N-N)(3,6-DBSQ)(3,6-DBCat): Subtle Diimine Ligand Effect (N-N=4,7-Dimethyl-1,10-phenanthroline, 5-Chloro-1,10-phenanthroline; DBSQ = Di-tert-butylsemiquinonato; DBCat = Di-tert-butylcatecholato). Bulletin of the Korean Chemical Society, 15, 8, (1994), 641-643. DOI: .

Search
(IN TITLE, AUTHOR, ABSTRACT,KEYWORDS)

Advanced Search ▼

POPULAR KEYWORDS
(TOP 10 KEYWORDS)

Recent Publications
(LAST 3 YEARS)

ISSN(Print) 0253-2964
ISSN(Online) 1229-5949