Preparation of Polyenaryloxynitriles from Dicyanovinyl Chloride and Diphenol Derivatives in the Presence of DABCO 


Vol. 21,  No. 11, pp. 1111-1114, Nov.  2000


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  Abstract

The kinetic study of the enaryloxynitriles via the nucleophilic vinylic substitution reaction of various phenol derivatives with 1-chloro-1-phenyl-2,2-dicyanoethene (1) was conducted in the presence of 1,4-diazabicyclo[2,2,2]octane (DABCO). Nucleophilic vinylic substitution of phenol derivatives with electrophilic olefins carrying sluggish leaving group involves a third-order reaction. The reaction was applied to solution polymerization of diphenol derivatives with p-bis(1-chrolo-2,2-dicyanovinyl)benzene (2), which yielded various polyenaryloxynitriles with moderate molecular weight.

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  Cite this article

[IEEE Style]

N. Geum and M. Gong, "Preparation of Polyenaryloxynitriles from Dicyanovinyl Chloride and Diphenol Derivatives in the Presence of DABCO," Bulletin of the Korean Chemical Society, vol. 21, no. 11, pp. 1111-1114, 2000. DOI: .

[ACM Style]

Neri Geum and Myoung-Seon Gong. 2000. Preparation of Polyenaryloxynitriles from Dicyanovinyl Chloride and Diphenol Derivatives in the Presence of DABCO. Bulletin of the Korean Chemical Society, 21, 11, (2000), 1111-1114. DOI: .

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ISSN(Print) 0253-2964
ISSN(Online) 1229-5949