Mass-analyzed Threshold Ionization Spectrometry with Scrambling Field Optimized for the Study of State-selective Ion Reaction Dynamics 


Vol. 23,  No. 9, pp. 1247-1252, Sep.  2002
10.5012/bkcs.2002.23.9.1247


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  Abstract

Mass-analyzed threshold ionization (MATI) technique is optimized to generate substantial amount of state-selected molecular ions sufficient for dynamics study. The main strategy is to stabilize intermediate (n = 100- 200) Rydberg states by l,m-mixing induced by AC field. Electrical jitter inherent in high voltage switching is utilized for this purpose. A related technique to locate the MATI onset is also described.

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  Cite this article

[IEEE Style]

S. T. Park, H. L. Kim, M. S. Kim, "Mass-analyzed Threshold Ionization Spectrometry with Scrambling Field Optimized for the Study of State-selective Ion Reaction Dynamics," Bulletin of the Korean Chemical Society, vol. 23, no. 9, pp. 1247-1252, 2002. DOI: 10.5012/bkcs.2002.23.9.1247.

[ACM Style]

Sang Tae Park, Hong Lae Kim, and Myung Soo Kim. 2002. Mass-analyzed Threshold Ionization Spectrometry with Scrambling Field Optimized for the Study of State-selective Ion Reaction Dynamics. Bulletin of the Korean Chemical Society, 23, 9, (2002), 1247-1252. DOI: 10.5012/bkcs.2002.23.9.1247.

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ISSN(Print) 0253-2964
ISSN(Online) 1229-5949