A Convenient Synthesis of Optically Active Unhindered Aliphatic Alcohols with High Optical Purity from Non-Racemic β-Hydroxy Sulfides 


Vol. 25,  No. 9, pp. 1385-1391, Sep.  2004
10.5012/bkcs.2004.25.9.1385


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  Abstract

A general route for the synthesis of optically active unhindered aliphatic alcohols, where the steric demands between two alkyl groups adjacent to the carbinol are similar, with high enantiomeric purity has been developed by sulfoxifation of chiral β-hydroxy sulfides, followed by alkylation and desulfurization.

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  Cite this article

[IEEE Style]

B. T. Cho and D. J. Kim, "A Convenient Synthesis of Optically Active Unhindered Aliphatic Alcohols with High Optical Purity from Non-Racemic β-Hydroxy Sulfides," Bulletin of the Korean Chemical Society, vol. 25, no. 9, pp. 1385-1391, 2004. DOI: 10.5012/bkcs.2004.25.9.1385.

[ACM Style]

Byung Tae Cho and Dong Jun Kim. 2004. A Convenient Synthesis of Optically Active Unhindered Aliphatic Alcohols with High Optical Purity from Non-Racemic β-Hydroxy Sulfides. Bulletin of the Korean Chemical Society, 25, 9, (2004), 1385-1391. DOI: 10.5012/bkcs.2004.25.9.1385.

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ISSN(Print) 0253-2964
ISSN(Online) 1229-5949