Structure of Mixed-Anions Tris(2-pyridylmethyl)amine Mn Complex, TPAMn(η2-NO3)(η-ClO4) 


Vol. 28,  No. 3, pp. 417-420, Mar.  2007
10.5012/bkcs.2007.28.3.417


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  Abstract

Mononuclear mixed-anions Mn complex of TPAMn(η2-N3)(η-Cl4), where TPA is tris(2-pyridylmethyl)-amine, has been synthesized and characterized. The neutral TPAMn(η2-N3)(η-Cl4) was obtained from the reaction between Mn(N32·42O and [3TPA](Cl43 in MeOH. X-ray crystallographic structure of mononuclear TPAMn(η2-N3)(η-Cl4) complex showed a seven-coordinated geometry with a tripodal tetradentate TPA, a terminal perchlorate and an η2-bound nitrate.

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  Cite this article

[IEEE Style]

B. Shin, M. Kim, J. Han, "Structure of Mixed-Anions Tris(2-pyridylmethyl)amine Mn Complex, TPAMn(η2-NO3)(η-ClO4)," Bulletin of the Korean Chemical Society, vol. 28, no. 3, pp. 417-420, 2007. DOI: 10.5012/bkcs.2007.28.3.417.

[ACM Style]

Bok-Kyu Shin, Mihyang Kim, and Jaehong Han. 2007. Structure of Mixed-Anions Tris(2-pyridylmethyl)amine Mn Complex, TPAMn(η2-NO3)(η-ClO4). Bulletin of the Korean Chemical Society, 28, 3, (2007), 417-420. DOI: 10.5012/bkcs.2007.28.3.417.

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ISSN(Print) 0253-2964
ISSN(Online) 1229-5949