Regioselective 1,3-Dipolar Cycloaddition and 1,2-Addition between Benzaldoxime NH-nitrone and Perfluoro-2-methyl-2-pentene 


Vol. 31,  No. 5, pp. 1172-1176, May  2010
10.5012/bkcs.2010.31.5.1172


PDF
  Abstract

Regioselective perfluorinated [3+2] cycloadducts and 1,2-adducts have been prepared by 1,3-dipolar cycloaddition between benzaldoxime NH-nitrone and perfluorinated alkene, perfluoro-2-methyl-2-pentene. Although the cycloaddition reaction is carried out at room temperature, the corresponding perfluorinated compounds are effectively produced in a high yield. In particular, the methoxy-substituted adducts (4 and 7a) show the self-assembled structure by intermolecular interactions. These derivatives were characterized by IR, 1H and 19F NMR, and the absolute structure of perfluorinated adducts was confirmed by X-ray crystallography.

  Statistics
Cumulative Counts from November, 2022
Multiple requests among the same browser session are counted as one view. If you mouse over a chart, the values of data points will be shown.


  Cite this article

[IEEE Style]

C. W. Lee, J. Y. Park, H. Kim, K. W. Chi, "Regioselective 1,3-Dipolar Cycloaddition and 1,2-Addition between Benzaldoxime NH-nitrone and Perfluoro-2-methyl-2-pentene," Bulletin of the Korean Chemical Society, vol. 31, no. 5, pp. 1172-1176, 2010. DOI: 10.5012/bkcs.2010.31.5.1172.

[ACM Style]

Chan Woo Lee, Joo Yuen Park, Hyunuk Kim, and Ki Whan Chi. 2010. Regioselective 1,3-Dipolar Cycloaddition and 1,2-Addition between Benzaldoxime NH-nitrone and Perfluoro-2-methyl-2-pentene. Bulletin of the Korean Chemical Society, 31, 5, (2010), 1172-1176. DOI: 10.5012/bkcs.2010.31.5.1172.

Search
(IN TITLE, AUTHOR, ABSTRACT,KEYWORDS)

Advanced Search ▼

POPULAR KEYWORDS
(TOP 10 KEYWORDS)

Recent Publications
(LAST 3 YEARS)

ISSN(Print) 0253-2964
ISSN(Online) 1229-5949