Origin of Exo/Endo Selectivity in the Intramolecular Diels-Alder Reaction 


Vol. 31,  No. 9, pp. 2527-2530, Sep.  2010
10.5012/bkcs.2010.31.9.2527


PDF
  Abstract

The stereoselectivity of the intramolecular Diels-Alder reactions of 1 and its derivatives were investigated by ab initio calculations. The stereoselectivity mainly originates from the steric repulsion and the orbital interactions. The additional s-cis and s-trans conformations by introducing the carbonyl group at the neighbor of diene or dienophile may change the stereoselectivity, hence this kind of substitution can be utilized for stereoselectivive asymmetric synthesis.

  Statistics
Cumulative Counts from November, 2022
Multiple requests among the same browser session are counted as one view. If you mouse over a chart, the values of data points will be shown.


  Cite this article

[IEEE Style]

S. Yan, D. H. Ryu, J. Y. Lee, "Origin of Exo/Endo Selectivity in the Intramolecular Diels-Alder Reaction," Bulletin of the Korean Chemical Society, vol. 31, no. 9, pp. 2527-2530, 2010. DOI: 10.5012/bkcs.2010.31.9.2527.

[ACM Style]

Shihai Yan, Do Hyun Ryu, and Jin Yong Lee. 2010. Origin of Exo/Endo Selectivity in the Intramolecular Diels-Alder Reaction. Bulletin of the Korean Chemical Society, 31, 9, (2010), 2527-2530. DOI: 10.5012/bkcs.2010.31.9.2527.

Search
(IN TITLE, AUTHOR, ABSTRACT,KEYWORDS)

Advanced Search ▼

POPULAR KEYWORDS
(TOP 10 KEYWORDS)

Recent Publications
(LAST 3 YEARS)

ISSN(Print) 0253-2964
ISSN(Online) 1229-5949