Synthesis and Characteristic of Novel Soluble Triazoleimide Oligomers with Terminated Arylacetylene 


Vol. 31,  No. 9, pp. 2603-2606, Sep.  2010
10.5012/bkcs.2010.31.9.2603


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  Abstract

Novel soluble triazoleimide oligomers terminated with arylacetylene terminated were synthesized by the Cu(I)-catalysed 1,3-dipolar cycloaddition polymerization of diazides and imide-containing dialkyne. Several molecular weight triazoleimide oligomers were prepared from diazide and dialkyne monomers with different stoichiometric combinations. The curing behaviors of the oligomers were tested by differential scanning calorimetry (DSC). The thermal properties of the cured products were evaluated by DSC and thermogravimetric analysis (TGA). These cured oligomers showed the glass transition temperature of about 225 - 235 oC and the decomposition temperature (at 5% weight loss) of about 385 - 393 oC in nitrogen.

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  Cite this article

[IEEE Style]

X. Zhou, L. Du, L. Wan, X. Wang, Y. E, F. Huang, "Synthesis and Characteristic of Novel Soluble Triazoleimide Oligomers with Terminated Arylacetylene," Bulletin of the Korean Chemical Society, vol. 31, no. 9, pp. 2603-2606, 2010. DOI: 10.5012/bkcs.2010.31.9.2603.

[ACM Style]

Xiao’an Zhou, Lei Du, Liqiang Wan, Xiaofei Wang, Yanpeng E, and Farong Huang. 2010. Synthesis and Characteristic of Novel Soluble Triazoleimide Oligomers with Terminated Arylacetylene. Bulletin of the Korean Chemical Society, 31, 9, (2010), 2603-2606. DOI: 10.5012/bkcs.2010.31.9.2603.

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ISSN(Print) 0253-2964
ISSN(Online) 1229-5949