Syntheses, Crystal Structures, and Spectral Properties of Two Coordination Compounds Based on 1,2-Bis(benzimidazolyl)benzene 


Vol. 32,  No. 3, pp. 1017-1021, Mar.  2011
10.5012/bkcs.2011.32.3.1017


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  Abstract

Two new benzimidazolyl-containing complexes have been synthesized by reactions of CuII salts and 1,2-bis(benzimidazolyl) benzene (2bbbz) with two different dicarboxylate ligands. When phthalate acid (2pt) was employed as secondary ligand, a 0D molecular complex Cu(2bbbz)(pt)·(2pt) (1) was furnished and when the secondary ligand was instead by a linear bridging ligand of terephthalic acid (2tp) a 1D zipper-like coordination polymer [Cu(2bbbz) (tp)·2(25OH)·2On (2) was obtained, suggesting the structure-direction effect of the secondary dicarbxylate ligand. The preliminary investigation on the spectral properties of the complexes was also presented.

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  Cite this article

[IEEE Style]

F. Y. Meng, B. L. Jiang, C. W. Lin, L. Wang, X. H. Tan, "Syntheses, Crystal Structures, and Spectral Properties of Two Coordination Compounds Based on 1,2-Bis(benzimidazolyl)benzene," Bulletin of the Korean Chemical Society, vol. 32, no. 3, pp. 1017-1021, 2011. DOI: 10.5012/bkcs.2011.32.3.1017.

[ACM Style]

Fa Yan Meng, Bing Li Jiang, Cui Wu Lin, Li Wang, and Xiao He Tan. 2011. Syntheses, Crystal Structures, and Spectral Properties of Two Coordination Compounds Based on 1,2-Bis(benzimidazolyl)benzene. Bulletin of the Korean Chemical Society, 32, 3, (2011), 1017-1021. DOI: 10.5012/bkcs.2011.32.3.1017.

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ISSN(Print) 0253-2964
ISSN(Online) 1229-5949