Extended Bifurcated Hydrogen Bonds Network Material of Copper(II) Complexes with 2-Dimethylaminomethyl-3-hydroxypyridine: Structures and Magnetic Properties 


Vol. 33,  No. 1, pp. 95-99, Jan.  2012
10.5012/bkcs.2012.33.1.95


PDF
  Tumbnail

  Abstract

Two novel copper(II) complexes, [Cu(dmamhp)(H2O)2(SO4)]n (1) and [Cu(dmamhp)(NO3)2(H2O)]·H2O (2) [dmamhp = 2-dimethylaminomethyl-3-hydroxypyridine] have been synthesized and structurally characterized by single crystal X-ray diffraction analysis. Compound 1 displays a double one-dimensional chains structure, in which each chain is constituted with the distorted octahedral copper(II) complex bridged through bidentate sulfate ligands resulting in a coordination polymer. The bifurcated hydrogen bonds and π-π interactions play important roles in the formation of the double chains structure. On the other hand, compound 2 adopts a distorted square pyramidal geometry around copper(II) ion and exists as a discrete monomer. There are intermolecular bifurcated hydrogen bonds and π-π stacking interactions between the monomeric units. The magnetic properties revealed that the paramagnetic behaviors are dominantly manifested and there are no intermolecular magnetic interactions in both compound 1 and 2.

  Statistics
Cumulative Counts from November, 2022
Multiple requests among the same browser session are counted as one view. If you mouse over a chart, the values of data points will be shown.


  Cite this article

[IEEE Style]

S. K. Kang, H. W. Lee, N. Sengottuvelan, Y. Kim, "Extended Bifurcated Hydrogen Bonds Network Material of Copper(II) Complexes with 2-Dimethylaminomethyl-3-hydroxypyridine: Structures and Magnetic Properties," Bulletin of the Korean Chemical Society, vol. 33, no. 1, pp. 95-99, 2012. DOI: 10.5012/bkcs.2012.33.1.95.

[ACM Style]

Sung Kwon Kang, Hong Woo Lee, Nallathambi Sengottuvelan, and Young-Inn Kim. 2012. Extended Bifurcated Hydrogen Bonds Network Material of Copper(II) Complexes with 2-Dimethylaminomethyl-3-hydroxypyridine: Structures and Magnetic Properties. Bulletin of the Korean Chemical Society, 33, 1, (2012), 95-99. DOI: 10.5012/bkcs.2012.33.1.95.

Search
(IN TITLE, AUTHOR, ABSTRACT,KEYWORDS)

Advanced Search ▼

POPULAR KEYWORDS
(TOP 10 KEYWORDS)

Recent Publications
(LAST 3 YEARS)

ISSN(Print) 0253-2964
ISSN(Online) 1229-5949