A Novel 3D Polypseudo-rotaxane Metal-organic Framework Based on a Flexible Bis-pyridyl-bis-amide Ligand 


Vol. 33,  No. 11, pp. 3793-3796, Nov.  2012
10.5012/bkcs.2012.33.11.3793


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  Abstract

A novel 3D compound {[Cu(L)(H2O)4][Cu2(SIP)2(L)2]}·2H2O (1) (L = N,N-bis(4-pyridinecarboxamide)-1,4- butane, SIP = 5-sulfoisophthalate) is hydrothermally synthesized. X-ray diffraction analysis reveals that compound 1 is composed of 2D anionic [Cu2(SIP)2(L)2]n 2n− double-layers and discrete 1D cationic [CuL(H2O)4]n 2n+ polymeric chains, which represents a rare 3D polypseudo-rotaxane MOF from intercalation of 1D and 2D framework. In addition, the luminescent property and electrochemical behavior of compound 1 have been investigated.

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  Cite this article

[IEEE Style]

X. Wang, N. Han, H. Lin, C. Xu, J. Luan, G. Liu, "A Novel 3D Polypseudo-rotaxane Metal-organic Framework Based on a Flexible Bis-pyridyl-bis-amide Ligand," Bulletin of the Korean Chemical Society, vol. 33, no. 11, pp. 3793-3796, 2012. DOI: 10.5012/bkcs.2012.33.11.3793.

[ACM Style]

Xiu-Li Wang, Na Han, Hong-Yan Lin, Chuang Xu, Jian Luan, and Guo-Cheng Liu. 2012. A Novel 3D Polypseudo-rotaxane Metal-organic Framework Based on a Flexible Bis-pyridyl-bis-amide Ligand. Bulletin of the Korean Chemical Society, 33, 11, (2012), 3793-3796. DOI: 10.5012/bkcs.2012.33.11.3793.

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ISSN(Print) 0253-2964
ISSN(Online) 1229-5949