Pd-Catalyzed Oxidative Arylation of Cinnamylphosphonates: An Efficient Synthesis of (Z)-Alkenylphosphonates 


Vol. 33,  No. 11, pp. 3817-3822, Nov.  2012
10.5012/bkcs.2012.33.11.3817


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  Abstract

Various alkenylphosphonates were prepared via the palladium-catalyzed oxidative arylation of cinnamylphosphonates with arenes. The regioselectivity during the β-H elimination of the corresponding alkylpalladium intermediate was governed most likely by steric factors.

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  Cite this article

[IEEE Style]

H. S. Lee, C. H. Lim, H. J. Lee, J. N. Kim, "Pd-Catalyzed Oxidative Arylation of Cinnamylphosphonates: An Efficient Synthesis of (Z)-Alkenylphosphonates," Bulletin of the Korean Chemical Society, vol. 33, no. 11, pp. 3817-3822, 2012. DOI: 10.5012/bkcs.2012.33.11.3817.

[ACM Style]

Hyun Seung Lee, Cheol Hee Lim, Hyun Ju Lee, and Jae Nyoung Kim. 2012. Pd-Catalyzed Oxidative Arylation of Cinnamylphosphonates: An Efficient Synthesis of (Z)-Alkenylphosphonates. Bulletin of the Korean Chemical Society, 33, 11, (2012), 3817-3822. DOI: 10.5012/bkcs.2012.33.11.3817.

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ISSN(Print) 0253-2964
ISSN(Online) 1229-5949