The Synthesis and Properties of Asymmetrically Substituted 4,4'-Bis(1,3,5-triazine-6- yl)diaminostilbene-2,2'-disulfonic Acid Derivatives as Fluorescent Brighteners [II] 


Vol. 34,  No. 7, pp. 2131-2137, Jul.  2013
10.5012/bkcs.2013.34.7.2131


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  Abstract

In this work, the key intermediate, 4-amino-4'-(2-amino-4-anilino-1,3,5-triazine-6-yl)-aminostilbene-2,2'-disulfonic acid, was prepared from 4-(2-amino-4-anilino-1,3,5-triazine-6-yl)amino-4'-nitrostilbene-2,2'-disulfonate by using Tin(II) chloride as the reducing agent. Using this intermediate, nineteen new asymmetrically substituted bistriazinylstilbene fluorescent brightening agents were synthesized. Chemical structures of the obtained compounds 5a-s were analyzed by proton NMR spectrum. The physical properties of the new compounds 5a-s were characterized by fastness test and whiteness measurement test and the obtained data were compared to measurements obtained from CI 86.

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  Cite this article

[IEEE Style]

J. Jung and Y. Kang, "The Synthesis and Properties of Asymmetrically Substituted 4,4'-Bis(1,3,5-triazine-6- yl)diaminostilbene-2,2'-disulfonic Acid Derivatives as Fluorescent Brighteners [II]," Bulletin of the Korean Chemical Society, vol. 34, no. 7, pp. 2131-2137, 2013. DOI: 10.5012/bkcs.2013.34.7.2131.

[ACM Style]

Jongkeun Jung and Yonghan Kang. 2013. The Synthesis and Properties of Asymmetrically Substituted 4,4'-Bis(1,3,5-triazine-6- yl)diaminostilbene-2,2'-disulfonic Acid Derivatives as Fluorescent Brighteners [II]. Bulletin of the Korean Chemical Society, 34, 7, (2013), 2131-2137. DOI: 10.5012/bkcs.2013.34.7.2131.