An Efficient Synthesis of Poly-Substituted Phenols and Pyridines from Morita-Baylis-Hillman Acetates and Diethyl Oxalacetate 


Vol. 34,  No. 10, pp. 3027-3032, Oct.  2013
10.5012/bkcs.2013.34.10.3027


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  Abstract

Various phenol derivatives were synthesized in a one-pot reaction from MBH acetates and sodium diethyl oxalacetate via a [4C+2C] cyclization protocol. In addition, some pyridine derivatives could also be synthesized using the same starting materials, by isolating the SN2' reaction intermediate and performing the cyclization with NH4OAc.

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  Cite this article

[IEEE Style]

J. Yu, K. H. Kim, H. J. Lee, J. N. Kim, "An Efficient Synthesis of Poly-Substituted Phenols and Pyridines from Morita-Baylis-Hillman Acetates and Diethyl Oxalacetate," Bulletin of the Korean Chemical Society, vol. 34, no. 10, pp. 3027-3032, 2013. DOI: 10.5012/bkcs.2013.34.10.3027.

[ACM Style]

Jin Yu, Ko Hoon Kim, Hyun Ju Lee, and Jae Nyoung Kim. 2013. An Efficient Synthesis of Poly-Substituted Phenols and Pyridines from Morita-Baylis-Hillman Acetates and Diethyl Oxalacetate. Bulletin of the Korean Chemical Society, 34, 10, (2013), 3027-3032. DOI: 10.5012/bkcs.2013.34.10.3027.

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ISSN(Print) 0253-2964
ISSN(Online) 1229-5949