Chromium(III) Complex Obtained from Dipicolinic Acid: Synthesis, Characterization, X-Ray Crystal Structure and Electrochemical Studies 


Vol. 34,  No. 10, pp. 3093-3097, Oct.  2013
10.5012/bkcs.2013.34.10.3093


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  Abstract

The synthesis, X-ray crystallography, spectroscopic (IR, UV-vis), and electrochemical properties of the title compound, [H3O][Cr(dipic)2] [H3O+.Cl−] (1), (H2dipic = 2,6-pyridinedicarboxylic acid), are reported. This complex crystallizes in the monoclinic space group Cc with a = 14.9006(10) Å, b = 12.2114(8) Å, c = 8.6337(6) Å, α = 90.00°, β = 92.7460(10)°, γ = 90.00°, and V = 1569.16(18) Å3 with Z = 4. The hydrogen bonding and noncovalent interactions play roles in the stabilization of the structure. In order to gain a better understanding of the most important geometrical parameters in the structure of the complex, atoms in molecules (AIM) method at B3LYP/6-31G level of theory has been employed.

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  Cite this article

[IEEE Style]

K. Ghasemi, A. R. Rezvani, I. A. Razak, A. Moghimi, F. Ghasemi, M. M. Rosli, "Chromium(III) Complex Obtained from Dipicolinic Acid: Synthesis, Characterization, X-Ray Crystal Structure and Electrochemical Studies," Bulletin of the Korean Chemical Society, vol. 34, no. 10, pp. 3093-3097, 2013. DOI: 10.5012/bkcs.2013.34.10.3093.

[ACM Style]

Khaled Ghasemi, Ali Reza Rezvani, Ibrahim Abdul Razak, Abolghasem Moghimi, Fatemeh Ghasemi, and Mohd Mustaqim Rosli. 2013. Chromium(III) Complex Obtained from Dipicolinic Acid: Synthesis, Characterization, X-Ray Crystal Structure and Electrochemical Studies. Bulletin of the Korean Chemical Society, 34, 10, (2013), 3093-3097. DOI: 10.5012/bkcs.2013.34.10.3093.

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ISSN(Print) 0253-2964
ISSN(Online) 1229-5949