The Influence of Collision Energy on the Reaction H+HS→H2+S 


Vol. 34,  No. 11, pp. 3350-3356, Nov.  2013
10.5012/bkcs.2013.34.11.3350


PDF
  Tumbnail

  Abstract

Quasi-classical trajectory calculations have been carried out for the reaction H+HS by using the newest triplet 3A" potential energy surface (PES). The effects of the collision energy and reagent initial rotational excitation are studied. The cross sections and thermal rate constants for the title reaction are calculated. The results indicate that the integral cross sections (ICSs) are sensitive to the collision energy and almost independent to the initial rotational states. The ro-vibrational distributions for the product H2 at different collision energies are presented. The investigations on the vector correlations are also performed. It is found that the collision energies play a postive role on the forward scatter of the product molecules. There is a negative influence on both the alignment and orientation of the product angular momentum for low collision energy at low energy region. Whereas the influence of collision energy is not obvious at high energy region.

  Statistics
Cumulative Counts from November, 2022
Multiple requests among the same browser session are counted as one view. If you mouse over a chart, the values of data points will be shown.


  Cite this article

[IEEE Style]

Y. Liu, H. Zhai, Z. Zhu, Y. Liu, "The Influence of Collision Energy on the Reaction H+HS→H2+S," Bulletin of the Korean Chemical Society, vol. 34, no. 11, pp. 3350-3356, 2013. DOI: 10.5012/bkcs.2013.34.11.3350.

[ACM Style]

Yanlei Liu, Hongsheng Zhai, Zunlue Zhu, and Yufang Liu. 2013. The Influence of Collision Energy on the Reaction H+HS→H2+S. Bulletin of the Korean Chemical Society, 34, 11, (2013), 3350-3356. DOI: 10.5012/bkcs.2013.34.11.3350.

Search
(IN TITLE, AUTHOR, ABSTRACT,KEYWORDS)

Advanced Search ▼

POPULAR KEYWORDS
(TOP 10 KEYWORDS)

Recent Publications
(LAST 3 YEARS)

ISSN(Print) 0253-2964
ISSN(Online) 1229-5949