Hydrothermal Synthesis, Crystal Structures and Properties of Zinc(II) Di-nuclear Complex and Copper(I) Coordination Polymer Based on Building Block 2-Phenyl-4,6-di(pyridin-2-yl)pyrimidine 


Vol. 34,  No. 12, pp. 3743-3748, Dec.  2013
10.5012/bkcs.2013.34.12.3743


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  Abstract

A tetradentate ligand of 2-phenyl-4,6-di(pyridin-2-yl)pyrimidine (L) has been synthesized and its complexes with ZnI2 and CuI have been obtained by hydrothermal method. single crystal X-ray diffraction analysis indicates that ligand L coordinates with Zn(II) ions to form a simple four-coordinate di-nuclear complex, while the complexation of L with Cu(I) constructs a one-dimensional chain polymer. The existence of I– ion hampers the L to assemble grid-type complexes with Zn(II) and Cu(I). Fluorescence spectra show that the L emits blue fluorescence while its Cu(I) polymer decrease the fluorescence intensity and Zn(II) complex quenches the fluorescence.

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  Cite this article

[IEEE Style]

P. Zhao, W. Jing, L. Jing, F. Jian, Y. Li, "Hydrothermal Synthesis, Crystal Structures and Properties of Zinc(II) Di-nuclear Complex and Copper(I) Coordination Polymer Based on Building Block 2-Phenyl-4,6-di(pyridin-2-yl)pyrimidine," Bulletin of the Korean Chemical Society, vol. 34, no. 12, pp. 3743-3748, 2013. DOI: 10.5012/bkcs.2013.34.12.3743.

[ACM Style]

Pusu Zhao, Wang Jing, Long Jing, Fangfang Jian, and Yufeng Li. 2013. Hydrothermal Synthesis, Crystal Structures and Properties of Zinc(II) Di-nuclear Complex and Copper(I) Coordination Polymer Based on Building Block 2-Phenyl-4,6-di(pyridin-2-yl)pyrimidine. Bulletin of the Korean Chemical Society, 34, 12, (2013), 3743-3748. DOI: 10.5012/bkcs.2013.34.12.3743.

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ISSN(Print) 0253-2964
ISSN(Online) 1229-5949