Excited-State Dynamics of Carotenoids Studied by Femtosecond Transient Absorption Spectroscopy 


Vol. 35,  No. 3, pp. 851-857, Mar.  2014
10.5012/bkcs.2014.35.3.851


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  Abstract

Carotenoids, natural antenna pigments in photosynthesis share a symmetric backbone of conjugated polyenes. Contrary to the symmetric and almost planar geometries of carotenoids, excited state structure and dynamics of carotenoids are exceedingly complex. In this paper, recent infrared and visible transient absorption measurements and excitation dependent dynamics of 8'-apo-β-caroten-8'-al and 7',7'-dicyano-7'-apo-β- carotene will be reviewed. The recent visible transient absorption measurements of 8'-apo-β-caroten-8'-al in polar and nonpolar solvents will also be introduced to emphasize the complex excited-state dynamics and unsolved problems in the S2 and S1 excited states.

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  Cite this article

[IEEE Style]

I. Lee, S. Lee, Y. Pang, "Excited-State Dynamics of Carotenoids Studied by Femtosecond Transient Absorption Spectroscopy," Bulletin of the Korean Chemical Society, vol. 35, no. 3, pp. 851-857, 2014. DOI: 10.5012/bkcs.2014.35.3.851.

[ACM Style]

Ingu Lee, Sebok Lee, and Yoonsoo Pang. 2014. Excited-State Dynamics of Carotenoids Studied by Femtosecond Transient Absorption Spectroscopy. Bulletin of the Korean Chemical Society, 35, 3, (2014), 851-857. DOI: 10.5012/bkcs.2014.35.3.851.